Oct 7, 2022 · The Investigation of a Switchable Iridium Catalyst for the Hydrogenation of Amides: A Case Study of C–O Versus C–N Bond Scission. Anne K. Ravn. and. Nomaan M. Rezayee *. ACS Catalysis 2022, 12, 19, 11927-11933 (Letter) Publication Date (Web): September 16, 2022. Abstract. Mar 7, 2023 · Fischer-Tropsch synthesis (FTS) provides a nonpetroleum route for the production of value-added α-olefins from syngas. However, regulating the product distribution to promote the formation of long-chain α-olefins while maintaining low selectivity to C1 byproducts (CO2 and CH4) remains a great challenge. Herein, a series of alkali metal-promoted Ru/SiO2 catalysts were synthesized to ... Converting renewable biomass into value-added chemicals is a promising strategy to reduce the dependence on fossil fuels. The development of efficient, stable, and cost-effective nonprecious metal catalytic materials is significant for biomass upgrading. Herein, the 5-hydroxymethylfurfural (HMF) dehydrogenation kinetics on the NiCo2 nanowire is tuned …The design of electrocatalysts capable of selectively reducing nitrate to ammonia is gaining interest as a means of transforming waste into fertilizers. However, most prior investigations of prototypical electrocatalysts, such as polycrystalline Pd and Pt, have focused on unraveling the mechanisms responsible for the selective reduction of nitrate to nitrogen …ACS on Campus. The American Chemical Society’s premier outreach program. Launched in 2010, we've hosted programming at hundreds of institutions around the world, bringing the world’s leaders in chemistry, publishing, research, science communication and career development right to your doorstep. Here, we proposed a computation-driven strategy to optimize structures of enzymes via simulation-based iterative saturation mutagenesis (ISM), aiming to stabilize the spatial effects of the TS with a TSA as a placeholder. This approach was applied to redesign structures of chitinase in order to increase its catalytic activity. After three ...Catalysis – selective catalytic reagents are superior to stoichiometric ones; they can minimize or eliminate waste, depending on the reaction, which is necessary to achieve greener chemistry Maximize Resource Efficiency – catalysis can offer more direct synthetic routes, optimizing the time, energy and materials required to make a desired ... Published by American Chemical Society. Enzymatic degradation of polyethylene terephthlate (PET) by polyester hydrolases is currently subject to intensive research, as it is considered as a potential eco-friendly recycling method for plastic waste. However, the substrate-binding mode and the molecular mechanism of enzymatic PET hydrolysis are ...The electrochemical urea oxidation reaction (UOR) on Ni has recently attracted much attention as part of the global effort to produce hydrogen from waste. Fe addition to Ni (hydro)oxides results in a significant enhancement of the rate of the oxygen evolution reaction (OER), and a similar role of Fe in the UOR has often been claimed. In …Nature has provided a fantastic array of enzymes that are responsible for essential biochemical functions but not usually suitable for technological applications. Not content with the natural repertoire, protein engineering holds promise to extend the applications of improved enzymes with tailored properties. However, engineering of robust proteins …ACS Catal. Website Demos & Tutorials. For Librarians & Account Managers. , and. , , and. 2024-02-11T07:44:30.911-08:00. Read the latest ASAP articles from the ACS Catalysis on ACS Publications, a trusted source for peer-reviewed journals. Anionic ligands containing a nonbonded lone pair (i.e., amido, thiolate) are well-known to cooperate with a metal center in bifunctional catalytic reactions. An NHC CoII(κ3-SNS) imine–dithiolate complex (Co-3) effects the selective hydroboration of aldehydes (vs ketones) in 4–30 min at a 1 mol % loading in benzene (NHC = 2,5 …Professor Mary P. Watson from the University of Delaware is the 2023 ACS Catalysis Lectureship winner for her innovative and impactful contributions to …When you purchase a Goodman air conditioner, you want to make sure that you are covered in the event of an issue. One way to do this is by registering your Goodman AC warranty. Thi...Are you preparing for the RSCIT exam? Want to boost your chances of success on the online test? Look no further. In this article, we will provide you with some valuable tips and tr...ACS Catalysis is dedicated to publishing original research on heterogeneous catalysis, homogeneous catalysis, and bio-catalysis. Application coverage includes life sciences, drug discovery ... We have developed an efficient gold-catalyzed C–O cross-coupling reaction of (hetero)aryl iodides with primary and secondary alcohols via an AuI–AuIII catalytic ...Hydrogen bond-based organocatalysts rely on networks of attractive noncovalent interactions (NCIs) to impart enantioselectivity. As a specific example, aryl pyrrolidine substituted urea, thiourea, and …ACS Catalysis publishes Letters, Articles, Perspectives, Reviews, Viewpoints, and Accounts. More details regarding manuscript types may be found in the Information for …The most widely used catalysts and processes for H2S-selective catalytic oxidation are overviewed in this review. Two kinds of catalysts have been investigated intensively: carbon-based catalysts (active carbon catalyst, carbon nanotube catalyst, and carbon nanofiber catalyst), metal oxide-based catalysts (metal oxide catalyst, oxide …Developing a cost-effective and highly efficient electrocatalyst with superior catalytic activity is crucial for clean and green water splitting, including the hydrogen evolution reaction (HER), the oxygen evolution reaction (OER), and the oxygen reduction reaction (ORR). The single-atom catalyst (SAC) is a breakthrough in industrial catalysis …Mar 11, 2022 · Multicomponent alloys are promising candidates as catalysts for hydrogen evolution reaction (HER) in aqueous solutions owing to the synergic effects between elements. However, due to the vast compositional space they occupy, identifying the optimum catalyst is challenging both computationally and experimentally. In this paper, we propose a scalable high-throughput bubble screening method that ... Atomically dispersed metal catalysts are hailed as the most promising catalyst category for oxygen electrocatalysis. However, the challenges in regulating electronic configuration and unveiling the mechanism on the atomic scale are hindering their practical implementation. Herein, we modulate the Co d-orbital electron configuration by …Anionic ligands containing a nonbonded lone pair (i.e., amido, thiolate) are well-known to cooperate with a metal center in bifunctional catalytic reactions. An NHC CoII(κ3-SNS) imine–dithiolate complex (Co-3) effects the selective hydroboration of aldehydes (vs ketones) in 4–30 min at a 1 mol % loading in benzene (NHC = 2,5 …Catalysis, Elements, Mathematical methods, Quality management In June, ACS Catalysis received its first impact factor (IF), a statistic that relates the frequency at …The AC Hotel Alicante, just outside the city center, checks all the boxes for modern decor, comfort, and service at an affordable price. We may be compensated when you click on pro...30 Jul 2020 ... ACS Catalysis cover image - April 2020. PNNL research, featured on the cover of ACS Catalysis, showed that certain crystal surfaces yield ...Herein, we report on a molecular catalyst embedding metal–organic framework (MOF) that enables enhanced photocatalytic CO2 reduction activity. A benchmark photocatalyst fac-ReBr(CO)3(4,4′-dcbpy) (dcbpy = dicarboxy-2,2′-bipyridine) and photosensitizer Ru(bpy)2(5,5′-dcbpy)Cl2 (bpy = 2,2′-bipyridine) were synergistically entrapped inside the cages of the nontoxic and inexpensive MIL-101 ... Oxidation of unactivated alkanes, which requires substantial energy for conversion to valuable organic chemicals, is a major challenge in both industry and academia. Herein, we describe how solvents affect and improve the catalytic oxidation ability of a mononuclear copper(II)–alkylperoxo complex, [CuII(iPr3-tren)(OOC(CH3)2Ph)]+ (1, …Development of heterogeneous catalysts for alcohol transformation into nitriles under oxidant-free conditions is a challenge. Considering the C–H activation on α-carbon of primary alcohols is the rate-determining step, decreasing the activation energy of C–H activation is critical in order to enhance the catalytic activity. Several NiM/Al2O3 …Abstract. Reducing CO 2 is a challenging chemical transformation that biology solves easily, with high efficiency and specificity. In particular, formate dehydrogenases are of great interest since they reduce CO 2 to formate, a valuable chemical fuel and hydrogen storage compound. The metal-dependent formate dehydrogenases of prokaryotes can ...Rhodium-catalyzed asymmetric arylation (RCAA) reactions provide one of the most straightforward and powerful ways to introduce aryl fragments in an enantioselective manner. The discovery of novel chiral ligands and catalytic systems is a major focus in generating optical chiralities for RCAA reactions. In the past decade, the …Rhodium-catalyzed asymmetric arylation (RCAA) reactions provide one of the most straightforward and powerful ways to introduce aryl fragments in an enantioselective manner. The discovery of novel chiral ligands and catalytic systems is a major focus in generating optical chiralities for RCAA reactions. In the past decade, the …Threonine aldolase (TA)-catalyzed aldol condensation is a powerful tool for C–C bond formation under mild conditions, but the low Cβ-stereoselectivity has hampered its wide application. A stepwise visual screening method was developed to measure the activity and stereoselectivity of threonine aldolase-catalyzed aldol condensation by …Dec 18, 2020 · The 10th year of ACS Catalysis was marked as the final year for the journal’s leadership by Founding Editor-in-Chief, Christopher W. Jones (Georgia Institute of Technology). Chris’s thoughtful leadership and vision guided the journal and its talented team of associate editors, editorial advisory board members, reviewers, and authors from ... This week we’re improving our public speaking skills with the help of expert Carmine Gallo, author of Talk Like TED: The 9 Public-Speaking Secrets of the World’s Top Minds, who tel...We have developed an efficient gold-catalyzed C–O cross-coupling reaction of (hetero)aryl iodides with primary and secondary alcohols via an AuI–AuIII catalytic ...Selective oxidation of H2S to sulfur is an efficient process for industrial applications and environmental requirement to reduce the residual H2S in the Claus technology to an ultralow content (<0.1 ppm) before releasing the off-gas into the atmosphere. Recently, numerous research studies have been devoted to the development of highly active, selective and …Apr 6, 2022 · Artificial enzymes, usually created by incorporating one or two abiological catalytic species into protein hosts, are becoming promising tools for biocatalysis. However, they are still far behind natural enzymes due to their limited active sites with low activity and selectivity. Here, we proposed a polymeric approach to generate artificial enzymes by combining proteins with organocatalytic ... Read research published in the ACS Catalysis Vol. 13 Issue 22 on ACS Publications, a trusted source for peer-reviewed journals.Are you a frequent shopper at Ace Hardware? If so, then you definitely want to take advantage of the My Ace Rewards program. This loyalty program is designed to reward customers li...ACS Catalysis (2016), 6 (12), 8239-8247 CODEN: ACCACS; ISSN: 2155-5435. (American Chemical Society) The electrochem. redn. of carbon dioxide (CO2) to ethanol (C2H5OH) and ethylene (C2H4) using renewable electricity is a viable method for the prodn. of these com. vital chems. Copper (Cu) and its oxides are by far the most effective ...Herein, we disclose a Ni-catalyzed 1,1-difunctionalization of unactivated terminal alkenes that enables the incorporation of two different heteroatom motifs across an olefin backbone, thus streamlining the access to α-aminoboronic acid derivatives from simple precursors. The method is characterized by its simplicity and generality across a …Are you a frequent shopper at Ace Hardware? If so, then you definitely want to take advantage of the My Ace Rewards program. This loyalty program is designed to reward customers li...Heterogeneous catalysis is one of the pillars of chemical and energy industries. As research on this important topic advances, heterogeneous catalysis will be a central science in driving the transition to their eventual carbon neutral operation due to the ease of separation and reusability. ... ACS and Elsevier journals. Prof. Luque was named ...3′-Phosphoadenosine-5′-phosphosulfate (PAPS) is a universal sulfate group donor for all biological sulfation reactions in living organisms. Ambitions to biomanufacture sulfate-containing compounds such as heparin and chondroitin sulfate also promote the study on PAPS in vitro synthesis. However, the established enzymatic synthesis of …Here, we proposed a computation-driven strategy to optimize structures of enzymes via simulation-based iterative saturation mutagenesis (ISM), aiming to stabilize the spatial effects of the TS with a TSA as a placeholder. This approach was applied to redesign structures of chitinase in order to increase its catalytic activity. After three ...ACS Catalysis (2015), 5 (2), 1283-1302 CODEN: ACCACS; ISSN: 2155-5435. (American Chemical Society) A review. The chem. of nickel N-heterocyclic carbene complexes is a research area that has blossomed over the last 10 years, and a large no. of new complexes with a variety of architectural motifs are now known.Dec 12, 2016 · The combination of sequential biocatalytic reactions, via non-natural synthetic cascades, is a rapidly developing field and leads to the generation of complex valuable chemicals from simple precursors. As the toolbox of available biocatalysts continues to expand, so do the options for biocatalytic retrosynthesis of a target molecule, leading to alternative routes employing enzymatic ... ACS Publications uses CrossCheck's iThenticate software to detect instances of similarity in submitted manuscripts. Your manuscript may be screened for similarity to published material. Learn more. Manuscripts must be submitted through the ACS Paragon Plus Environment. Please review the Author Guidelines before beginning your manuscript submission. Dec 2, 2022 · Artwork by chemistry graduate student, Alison Sy-min Chang, featured in ACS' DEIR Cover Art series. A group of STEM individuals with varying identities are working in tandem with one another to harvest the energy from the sun to develop a collective catalytic system that addresses the initial disassembly of the systemic blockades in STEM. In her editorial, she reflects on the influence that ... The covalent organic framework COFbpyMn imposes mechanical constraints on the catalytically active centers, preventing the formation of Mn dimeric species, which results in a catalytic enhancement regarding the molecular counterpart. This study supports the importance of well-defined single-atom catalysis and the rational design of catalytic reticular materials. View the article. In today’s digital age, having a strong online presence is crucial for businesses, especially for ace online stores. With the increasing popularity of e-commerce, it’s important to...Cu single-atom catalysts (SACs) supported on CeO2–TiO2 were prepared by a sol–gel method and tested for CO oxidation between 120 and 350 °C. Operando and in situ spectroscopic methods including diffuse reflectance infrared Fourier transform (DRIFT), electron paramagnetic resonance (EPR), and near ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) combined with other basic ... Check out the latest edition of the ACS Catalysis on ACS Publications, a trusted source for peer-reviewed journals. Applied Catalysis B: Environment and Energy warmly welcomes original, innovative, and high-impact contributions within the realm encompassing thermo-, electro-, and photocatalysis to advance clean energy and provide sustainable environmental solutions. We encourage submissions that explore: Fundamental and applied catalysis research, …Codesignal is an online platform that helps employers assess the coding skills of potential candidates. It is a great way to quickly and accurately evaluate a candidate’s coding ab...An efficient method for the construction of 12-membered heterocycles with a trifluoromethyl group (3) was achieved via a nondecarboxylative Pd-catalyzed [6 + 6] annulation of six-membered trifluoromethyl benzo[d][1,3]oxazinones (1) with four-membered vinyl oxetanes (2). A variety of relatively large heterocycles 3 featuring a stereogenic …May 2, 2023 · Plasmonic catalysis is an ever-growing field in which chemical reactions are enabled by visible light excitation. The plasmonic effects provide a unique reaction environment, which can greatly affect chemical reaction processes. On the basis of extensive research on plasmon-induced chemical reactions, we focus on the fundamentals of plasmon-mediated catalytic selectivity and summarize recent ... Mar 11, 2022 · Multicomponent alloys are promising candidates as catalysts for hydrogen evolution reaction (HER) in aqueous solutions owing to the synergic effects between elements. However, due to the vast compositional space they occupy, identifying the optimum catalyst is challenging both computationally and experimentally. In this paper, we propose a scalable high-throughput bubble screening method that ... Apr 6, 2022 · Artificial enzymes, usually created by incorporating one or two abiological catalytic species into protein hosts, are becoming promising tools for biocatalysis. However, they are still far behind natural enzymes due to their limited active sites with low activity and selectivity. Here, we proposed a polymeric approach to generate artificial enzymes by combining proteins with organocatalytic ... University of California Santa Barbara. United States. E-mail: [email protected]. Read research published in the ACS Catalysis Vol. 13 Issue 6 on ACS Publications, a trusted source for peer-reviewed journals. ACS Catalysis (2016), 6 (12), 8239-8247 CODEN: ACCACS; ISSN: 2155-5435. (American Chemical Society) The electrochem. redn. of carbon dioxide (CO2) to ethanol (C2H5OH) and ethylene (C2H4) using renewable electricity is a viable method for the prodn. of these com. vital chems. Copper (Cu) and its oxides are by far the most effective ...Published by American Chemical Society. Enzymatic degradation of polyethylene terephthlate (PET) by polyester hydrolases is currently subject to intensive research, as it is considered as a potential eco-friendly recycling method for plastic waste. However, the substrate-binding mode and the molecular mechanism of enzymatic PET hydrolysis are ...Here, various biomass (glucose, sucrose, starch, cellulose, and paperboard) was converted to hydrothermal carbonaceous carbon (HTCC) photocatalysts for H 2 O 2 synthesis in pure water. The apparent quantum yield and synthesis rate could reach 18.2% (at 420 nm) and 1.16 mmol g cat–1 h –1, respectively. Importantly, HTCC can be …Cu single-atom catalysts (SACs) supported on CeO2–TiO2 were prepared by a sol–gel method and tested for CO oxidation between 120 and 350 °C. Operando and in situ spectroscopic methods including diffuse reflectance infrared Fourier transform (DRIFT), electron paramagnetic resonance (EPR), and near ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) combined with other basic ... Hydrogen peroxide is a valuable chemical oxidant with a wide range of applications in a variety of industrial processes, especially in water sanitization. Electrochemical synthesis of hydrogen peroxide (H2O2) through a two-electron oxygen reduction reaction (2e-ORR) or a two-electron water oxidation reaction (2e-WOR) has emerged as an appealing process …Heteroatom doping can facilitate intrinsic activity via the tuning of electronic states. However, it is still rare to elucidate the role of a specific metal sulfide electronic state and simultaneously enhance the CO2 electroreduction reaction (CO2RR) stability. SnS is well-known for its ability to produce HCOOH; however, its long-term operational stability …Herein, we describe the design and development a new nickel pincer complex that catalyzes the direct coupling of primary alkyl halides with terminal alkynes at ...The latest published issue of ACS Catalysis. See all articles . Interfacial Spontaneous Reduction Strategy to Synthesize Low-Valent Pt Single-Atom Catalyst for Boosting Hydrosilylation Metal hydrides (MHs) are featured for their reversible hydrogen absorption and desorption properties, which are conventionally used as hydrogen storage materials. …Dr. Buonsanti is an expert in catalysis and materials chemistry focusing on the design and use of nanomaterials to drive chemical, electrochemical, and …The enantioselective reduction of enamides is an efficient and atom-economical way to construct chiral amine motifs. In contrast to transition-metal complex based asymmetric hydrogenation, an alternative biocatalytic way is more sustainable but remains unexploited. The challenge lies in the redox potential mismatch between the …Herein, we report on a molecular catalyst embedding metal–organic framework (MOF) that enables enhanced photocatalytic CO2 reduction activity. A benchmark photocatalyst fac-ReBr(CO)3(4,4′-dcbpy) (dcbpy = dicarboxy-2,2′-bipyridine) and photosensitizer Ru(bpy)2(5,5′-dcbpy)Cl2 (bpy = 2,2′-bipyridine) were synergistically entrapped inside the cages of the nontoxic and inexpensive MIL-101 ... Here, we proposed a computation-driven strategy to optimize structures of enzymes via simulation-based iterative saturation mutagenesis (ISM), aiming to stabilize the spatial effects of the TS with a TSA as a placeholder. This approach was applied to redesign structures of chitinase in order to increase its catalytic activity. After three ...Catalysis – selective catalytic reagents are superior to stoichiometric ones; they can minimize or eliminate waste, depending on the reaction, which is necessary to achieve greener chemistry Maximize Resource Efficiency – catalysis can offer more direct synthetic routes, optimizing the time, energy and materials required to make a desired ... Herein, we report on a molecular catalyst embedding metal–organic framework (MOF) that enables enhanced photocatalytic CO2 reduction activity. A benchmark photocatalyst fac-ReBr(CO)3(4,4′-dcbpy) (dcbpy = dicarboxy-2,2′-bipyridine) and photosensitizer Ru(bpy)2(5,5′-dcbpy)Cl2 (bpy = 2,2′-bipyridine) were synergistically entrapped inside the cages of the nontoxic and inexpensive MIL-101 ... Seawater electrolysis is an attractive approach for producing clean hydrogen fuel in scenarios where freshwater is scarce and renewable electricity is abundant. However, chloride ions (Cl–) in seawater can accelerate electrode corrosion and participate in the undesirable chlorine evolution reaction (CER). This problem is especially acute in acidic …While Fe–N–C materials exhibit great potential for catalyzing the oxygen reduction reaction (ORR), their activity origin, especially the significant activity difference in acidic and alkaline media, remains a long-standing conundrum hindering the development of such catalysts. Here, we show an unanticipated pH-dependent regulation mechanism ...Jun 3, 2021 · Metal–organic frameworks (MOFs) as electrocatalysts for oxygen evolution reaction (OER) typically suffer from fast degradation under harsh electrolyte conditions, impeding their practical use in industrial electrolyzers. Besides, the evolution of catalytic centers in MOFs and the related influence on their performance along the progress of reaction have rarely been studied. Here, we report a ... Here, various biomass (glucose, sucrose, starch, cellulose, and paperboard) was converted to hydrothermal carbonaceous carbon (HTCC) photocatalysts for H 2 O 2 synthesis in pure water. The apparent quantum yield and synthesis rate could reach 18.2% (at 420 nm) and 1.16 mmol g cat–1 h –1, respectively. Importantly, HTCC can be …ACS Catalysis focuses on original research into heterogeneous catalysis, molecular catalysis, and biocatalysis – taking in a wide range of disciplines from the life sciences and organometallics to photochemistry and electrochemistry, drug discovery, materials science, environmental protection, polymers, and energy and fuels. While Fe–N–C materials exhibit great potential for catalyzing the oxygen reduction reaction (ORR), their activity origin, especially the significant activity difference in acidic and alkaline media, remains a long-standing conundrum hindering the development of such catalysts. Here, we show an unanticipated pH-dependent regulation mechanism ...Hydrogen is important because it is involved in the process of enzyme catalysis and because it stabilizes things like nucleic acids and proteins. Hydrogen bonds with many different...
Issue Publication Information. ACS Catalysis 2023, 13, 20, XXX-XXX (Article) Publication Date (Web): October 20, 2023. First Page. PDF. Read research published in the ACS Catalysis Vol. 13 Issue 20 on ACS Publications, a trusted source for peer-reviewed journals. . Donzi boats for sale
1,3,4-Oxadiazolines can be activated by triplet energy transfer catalysis under visible-light irradiation. The generated carbenes react with electron-poor olefins, giving valuable spirocyclopropanes. Mechanistic investigations, both theoretical and experimental, uncover plausible pathways and highlight the importance of the triplet energy transfer steps. View …ACS Catalysis Highlights Its Most Cited Papers from Around the Globe: Italy and Switzerland Christopher W. Jones ACS Catalysis 2020, 10, 5, 3514-3515 (Editorial) …Selective oxidation of H2S to sulfur is an efficient process for industrial applications and environmental requirement to reduce the residual H2S in the Claus technology to an ultralow content (<0.1 ppm) before releasing the off-gas into the atmosphere. Recently, numerous research studies have been devoted to the development of highly active, selective and …ACE inhibitors are medicines that are used in the treatment of high blood pressure and heart failure. A common side-effect is a persistent dry cough. Try our Symptom Checker Got an...Are you preparing for the RSCIT exam? Want to boost your chances of success on the online test? Look no further. In this article, we will provide you with some valuable tips and tr...The key of syngas (a mixture of CO and H2) chemistry lies in controlled dissociative activation of CO and C–C coupling. We demonstrate here that a bifunctional catalyst of partially reducible manganese oxide in combination with SAPO-34 catalyzes the selective formation of light olefins, which validates the generality of the OX-ZEO (oxide …Dec 2, 2022 · Artwork by chemistry graduate student, Alison Sy-min Chang, featured in ACS' DEIR Cover Art series. A group of STEM individuals with varying identities are working in tandem with one another to harvest the energy from the sun to develop a collective catalytic system that addresses the initial disassembly of the systemic blockades in STEM. In her editorial, she reflects on the influence that ... CO2 hydrogenation over Fe-based catalysts is a promising pathway to mitigate emissions of this greenhouse gas and provides a possibility for crude-oil-free production of chemicals and fuels. Understanding of (i) the role of crystalline phases or/and surface species in the working catalysts, (ii) the factors affecting their formation under …Abstract. Reducing CO 2 is a challenging chemical transformation that biology solves easily, with high efficiency and specificity. In particular, formate dehydrogenases are of great interest since they reduce CO 2 to formate, a valuable chemical fuel and hydrogen storage compound. The metal-dependent formate dehydrogenases of prokaryotes can ... Biomolecular self-assembly, typically with de novo designed peptide or DNA as the building blocks, provides an effective avenue to orient and confine reactive groups into a catalytically active configuration to mimic and even rival the catalytic performance of native enzymes. In this Review, we discuss the chemical and structural properties of ...We report here selective reduction of CO to acetate using Cu–Pd bimetallic electrocatalysts. High activity and selectivity are demonstrated for CO-to-acetate conversion with >200 mA/cm 2 in geometric current density and >65% in Faradaic efficiency (FE). An asymmetrical C–C coupling mechanism is proposed to explain the composition …ACS Publications uses CrossCheck's iThenticate software to detect instances of similarity in submitted manuscripts. Your manuscript may be screened for similarity to published material. Learn more. Manuscripts must be submitted through the ACS Paragon Plus Environment. Please review the Author Guidelines before beginning your manuscript submission. ACS Catalysis (2019), 9 (9), 7840-7861 CODEN: ACCACS; ISSN: 2155-5435. (American Chemical Society) A review. Catalytic hydrogenation of CO2 with renewable H2 to methanol represents a promising pathway for reducing anthropogenic CO2 emissions. Catalysts play a key role in enhancing both the hydrogenation ...The persistently increasing energy consumption and the low abundance of conventional fuels have raised serious concerns all over the world. Thus, the development of technology for clean-energy production has become the major research priority worldwide. The globalization of advanced energy conversion technologies like rechargeable metal–air ….
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